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COMPLEMENTS OF ORGANIC CHEMISTRY

CODE 80286
ACADEMIC YEAR 2018/2019
CREDITS 6 credits during the 1st year of 9018 Chemical Sciences (LM-54) GENOVA
SCIENTIFIC DISCIPLINARY SECTOR CHIM/06
LANGUAGE Italian
TEACHING LOCATION GENOVA (Chemical Sciences)
SEMESTER 2° Semester
TEACHING MATERIALS AULAWEB

AIMS AND CONTENT

SYLLABUS/CONTENT

  • Advanced stereochemistry concepts: a) symmetry properties of organic molecules: symmetry elements and point groups; b) conformations of acyclic and cyclic molecules; c) chirality of molecules without stereogenic centers (allenes, biphenyls, etc.); d) prostereoisomerism
  • Methods for the experimental determination of the enantiomeric excess
  • Enantio- and diastereoselective reactions [stoichiometric reactions, catalytic reactions (organometal catalysis and organocatalysis), use of chiral auxiliaries]
  • Examples of enantio- and diastereoselective reactions: reductions of C=C and C=O bonds, C-C and C=C bond forming reactions, oxidations etc. In particular catalytic reaction will be deeper investigated
  • Claisen rearrangement
  • [4+2] Cycloadditions: the Diels-Alder reaction

TEACHERS AND EXAM BOARD

Exam Board

LUCA BANFI (President)

RENATA RIVA (President)

CHIARA LAMBRUSCHINI

LISA MONI

LESSONS

EXAMS

Exam schedule

Date Time Location Type Notes
29/01/2019 15:00 GENOVA Orale
21/02/2019 15:00 GENOVA Orale
19/06/2019 15:00 GENOVA Orale
09/07/2019 15:00 GENOVA Orale
24/07/2019 15:00 GENOVA Orale
10/09/2019 15:00 GENOVA Orale
01/10/2019 15:00 GENOVA Orale