CODE 80286 ACADEMIC YEAR 2017/2018 CREDITS 6 cfu anno 1 SCIENZE CHIMICHE 9018 (LM-54) - SCIENTIFIC DISCIPLINARY SECTOR CHIM/06 LANGUAGE Italian TEACHING LOCATION SEMESTER 2° Semester AIMS AND CONTENT SYLLABUS/CONTENT Advanced stereochemistry concepts: a) symmetry properties of organic molecules: symmetry elements and point groups; b) conformations of acyclic and cyclic molecules; c) chirality of molecules without stereogenic centers (allenes, biphenyls, etc.); d) prostereoisomerism Methods for the experimental determination of the enantiomeric excess Enantio- and diastereoselective reactions [stoichiometric reactions, catalytic reactions (organometal catalysis and organocatalysis), use of chiral auxiliaries] Examples of enantio- and diastereoselective reactions: reductions of C=C and C=O bonds, C-C and C=C bond forming reactions, oxidations etc. In particular catalytic reaction will be deeper investigated Claisen rearrangement [4+2] Cycloadditions: the Diels-Alder reaction TEACHERS AND EXAM BOARD RENATA RIVA Ricevimento: I'm available every day of the week. Please, contact me before by e-mail for an appointment. Exam Board RENATA RIVA (President) LUCA BANFI LARA BIANCHI LISA MONI LESSONS Class schedule COMPLEMENTS OF ORGANIC CHEMISTRY EXAMS Exam schedule Data appello Orario Luogo Degree type Note 30/01/2018 15:00 GENOVA Orale 22/02/2018 15:00 GENOVA Orale 19/06/2018 09:00 GENOVA Orale 03/07/2018 09:00 GENOVA Orale 17/07/2018 09:00 GENOVA Orale 11/09/2018 15:00 GENOVA Orale 02/10/2018 15:00 GENOVA Orale 17/10/2018 14:00 GENOVA Orale
