CODE 80286 ACADEMIC YEAR 2019/2020 CREDITS 6 cfu anno 1 SCIENZE CHIMICHE 9018 (LM-54) - GENOVA SCIENTIFIC DISCIPLINARY SECTOR CHIM/06 LANGUAGE Italian TEACHING LOCATION GENOVA SEMESTER 2° Semester TEACHING MATERIALS AULAWEB AIMS AND CONTENT SYLLABUS/CONTENT Advanced stereochemistry concepts: a) symmetry properties of organic molecules: symmetry elements and point groups; b) conformations of acyclic and cyclic molecules; c) chirality of molecules without stereogenic centers (allenes, biphenyls, etc.); d) prostereoisomerism Methods for the experimental determination of the enantiomeric excess Enantio- and diastereoselective reactions [stoichiometric reactions, catalytic reactions (organometal catalysis and organocatalysis), use of chiral auxiliaries] Examples of enantio- and diastereoselective reactions: reductions of C=C and C=O bonds, C-C and C=C bond forming reactions, oxidations etc. In particular catalytic reaction will be deeper investigated Claisen rearrangement [4+2] Cycloadditions: the Diels-Alder reaction TEACHERS AND EXAM BOARD RENATA RIVA Ricevimento: I'm available every day of the week. Please, contact me before by e-mail for an appointment. Exam Board LUCA BANFI (President) RENATA RIVA (President) CHIARA LAMBRUSCHINI LISA MONI EXAMS Exam schedule Data appello Orario Luogo Degree type Note 28/01/2020 15:00 GENOVA Orale 20/02/2020 15:00 GENOVA Orale 25/06/2020 15:00 GENOVA Orale 07/07/2020 15:00 GENOVA Orale 22/07/2020 15:00 GENOVA Orale 08/09/2020 15:00 GENOVA Orale 01/10/2020 15:00 GENOVA Orale
