CODE 80286 ACADEMIC YEAR 2016/2017 CREDITS 6 cfu anno 2 SCIENZE CHIMICHE 9018 (LM-54) - 6 cfu anno 1 SCIENZE CHIMICHE 9018 (LM-54) - SCIENTIFIC DISCIPLINARY SECTOR CHIM/06 LANGUAGE Italiano TEACHING LOCATION SEMESTER 2° Semester AIMS AND CONTENT SYLLABUS/CONTENT Advanced stereochemistry concepts: a) symmetry properties of organic molecules: symmetry elements and point groups; b) conformations of acyclic and cyclic molecules; c) chirality of molecules without stereogenic centers (allenes, biphenyls, etc.); d) prostereoisomerism Methods for the experimental determination of the enantiomeric excess Enantio- and diastereoselective reactions [stoichiometric reactions, catalytic reactions (organometal catalysis and organocatalysis), use of chiral auxiliaries] Examples of enantio- and diastereoselective reactions: reductions of C=C and C=O bonds, C-C and C=C bond forming reactions, oxidations etc. In particular catalytic reaction will be deeper investigated Claisen rearrangement [4+2] Cycloadditions: the Diels-Alder reaction TEACHERS AND EXAM BOARD RENATA RIVA Exam Board RENATA RIVA (President) LUCA BANFI LARA BIANCHI LISA MONI EXAMS Exam schedule Data appello Orario Luogo Degree type Note 13/06/2017 09:00 GENOVA Orale 04/07/2017 09:00 GENOVA Orale 18/07/2017 09:00 GENOVA Orale 12/09/2017 09:00 GENOVA Orale 03/10/2017 15:00 GENOVA Orale