CODE 91048 ACADEMIC YEAR 2025/2026 CREDITS 5 cfu anno 3 SCIENZE AMBIENTALI E NATURALI 9916 (L-32) - GENOVA SCIENTIFIC DISCIPLINARY SECTOR CHIM/01 LANGUAGE Italian TEACHING LOCATION GENOVA SEMESTER Annual PREREQUISITES Propedeuticità in ingresso Per sostenere l'esame di questo insegnamento è necessario aver sostenuto i seguenti esami: ENVIRONMENTAL AND NATURAL SCIENCES 9916 (coorte 2023/2024) FUNDAMENTALS OF CHEMISTRY 72889 2023 TEACHING MATERIALS AULAWEB AIMS AND CONTENT LEARNING OUTCOMES This teaching provides general information on methods used for chemical analyses and examples of the theoretical-practical approach to the study of environmental chemical problems, with particular regards to the procedures commonly used for research and environmental monitoring of the coastal marine areas. AIMS AND LEARNING OUTCOMES The course provides general information on analytical methods and examples of theoretical-practical approach to the study of environmental chemical problems, with particular regards to the procedures commonly used for research and environmental monitoring of the coastal marine area. It allows the student to apply the concepts assimilated in the previous chemistry courses and in the theoretical part of this teaching, through some exercises in volumetric and instrumental analysis. At the end of the course the student must be able to: - describe the theory of volumetric analysis for the different chemical equilibria (acid-base, precipitation, complexation, oxidation-reduction) - construct the relevant titration curves theoretically; choose the suitable indicator for a specific titration; predict the influence of experimental conditions on the titration performance - apply the theoretical knowledge acquired by carrying out various volumetric analyzes of different types in the laboratory PREREQUISITES Fundamentals of chemistry (I year) Analytical Chemistry (III year, first semester) TEACHING METHODS Attendance at lectures is strongly recommended, even if not mandatory; It is necessary to participate in practical laboratory exercises and to write a technical report on the results to take the exam. The slides of the lessons and the analytical protocols for practical exercises in the laboratory are published and made available on AULAWEB. "Students who have valid certification of physical or learning disabilities on file with the University and who wish to discuss possible accommodations or other circumstances regarding lectures, coursework and exams, should speak both with the instructor and with Professor Sara Ferrando (sara.ferrando@unige.it), the Department’s disability liaison.” SYLLABUS/CONTENT Volumetric Analysis. Laboratory equipment. Theoretical aspects of volume. Titration curves Precipitation titrations (Mohr, Fajans and Volhard methods). Neutralization titrations. PH indicators. Complexometric titrations. Influence of pH on the EDTA dissociation. Distribution rate (a), predominantly graphs (a / pH). Metallochromic indicators (Neroeriocromo T). Oxidation-reduction process and Nerst equation. Construction of symmetrical and asymmetrical titration curves. Redox and specific indicators (salda d’amido). Characteristics of KMnO4 and its applications in redox titrations. Laboratory exercises: 4 exercises in volumetric analysis (pH of natural water, seawater halides, drinking water hardness, dissolved oxygen). RECOMMENDED READING/BIBLIOGRAPHY - Skoog, West, Holler, Chimica Analitica. Una Introduzione, EdiSES - D.C.Harris, Chimica Analitica Quantitativa, Zanichelli - D.A.Skoog, D.M.West, Introduzione alla chimica analitica, Piccin - Skoog, West, Holler, Crouch, Fondamenti di Chimica Analitica, EdiSES TEACHERS AND EXAM BOARD EMANUELE MAGI Ricevimento: Each business day, by appointment PAOLA FRANCESCA RIVARO Ricevimento: The students are able to book an appointment by mail (paola.rivaro@unige.it) or by aulaweb. LESSONS LESSONS START The lessons of the first semester will start in September/October 2024. Refer to the detailed timetable below link: https://easyacademy.unige.it/portalestudenti/ Class schedule ENVIRONMENTAL APPLIED CHEMISTRY LABORATORY EXAMS EXAM DESCRIPTION Students wishing to take the exam must book at least two days in advance on: https://servizionline.unige.it/studenti/esami/prenotazione The exam is oral, has a duration of about 30 minutes and includes questions on topics specified in the detailed program that is illustrated to students and deposited on AulaWeb, incliding questions on the practical laboratory part. The student will have to demonstrate that he has achieved the educational objectives both by exposing the topics orally and by writing down possible chemical reactions, formulas, graphs and diagrams related to the questions. If the commission considers that these objectives have not been achieved, the student will be asked to withdraw. ASSESSMENT METHODS The oral test is aimed at assessing the knowledge and understanding of the subject, based on the training objectives described above; the ability to link the various topics is evaluated. The exam is always conducted by two tenured professors and is conducted in such a way as to evaluate not only if the student has acquired the required knowledge, but also if he has deeply understood the topics and if he is able to apply them to simple analytical problems. Considering that at least one of the two professors has many years of teaching experience in the discipline, the commission is able to accurately verify the achievement of the educational objectives of teaching. If these are not reached, the student is invited to deepen the study and, if necessary, to ask further explanations to the teacher. FURTHER INFORMATION Regular attendance is recommended as it facilitates the understanding; participation in most practical laboratory exercises is required. 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