CODE 66881 ACADEMIC YEAR 2018/2019 CREDITS 8 cfu anno 1 BIOTECNOLOGIE 8756 (L-2) - GENOVA SCIENTIFIC DISCIPLINARY SECTOR CHIM/03 LANGUAGE Italian TEACHING LOCATION GENOVA SEMESTER 1° Semester PREREQUISITES Propedeuticità in uscita Questo insegnamento è propedeutico per gli insegnamenti: Biotechnology 8756 (coorte 2018/2019) BIOCHEMISTRY AND LABORATORY 66895 Biotechnology 8756 (coorte 2018/2019) PHARMACEUTICAL CHEMISTRY AND PHARMACEUTICAL BIOTECHNOLOGY AND LABORATORY COURSE 80799 Biological monitoring 9016 (coorte 2018/2019) RADIOCHEMISTRY 28078 TEACHING MATERIALS AULAWEB OVERVIEW This is a General and Inorganic chemistry course. Being of basic level, the most of the subject is part of students backìground. On the other hand, they will be resumed, studied in deep and widened, according to the knowledge necessary at University level. AIMS AND CONTENT LEARNING OUTCOMES Aim of the course is giving the students basic elements of general and inorganic chemistry, driving them to language and method of chemistry, supplying the necessary tools for a better understanding of chemical aspects in the following courses to be attended in their university studies. AIMS AND LEARNING OUTCOMES Aim of the course is giving the students the basic elements of general and inorganic chemistry, driving them to language and method of chemistry, and supplying the necessary tools for a better understanding of chemical aspects in the courses to be attended through their university studies. PREREQUISITES The only prerequisite is having attended a course of general and Inorgamic chemistry at the College. This is not mandatory on the formal point of view. However, the absence of a background should render very difficult attendind a course based on retrieve and deepening general and inorganic chemistry basic notions TEACHING METHODS Teaching methods The course is provided through lectures and numerical exercises sessions. We also carry out various laboratory exercises, for which attendance is mandatory. The teaching materials used are mostly reported in the Aulaweb site. SYLLABUS/CONTENT Syllabus, contents. General introduction. Homogeneous and heterogeneous systems. Pure substances, solutions of different types. Atoms and molecules. Geometric lattices, atomic number, atomic and molecular mass. Empiric and molecular formulae. Formulae and reactions stoichiometry. Oxidation number. Systematic inorganic chemistry. Reaction types classification. Reaction balance. Atomic structure. Atomic orbitals and their representation. Aufbau rules. Electronic configuration of elements. Periodic properties. Chemical bond. Ionic and covalent bond. Octet rule. Valence bond (VB) theory. Hybrid orbitals. VSEPR theory. Intermolecular forces. Chemical equilibrium. Equilibrium constant. Factors influencing chemical equilibrium. Ionic equilibria in aqueous solution. Molecular and ionic solutions. Methods to indicate concentration. Ionic product of water. Acidity, basicity and related equilibrium constants. pH and pOH. Acids and bases: theories of Arrhenius, Brönsted and Lewis. Calculation of pH for strong and weak acids and bases. Hydrolysis of salts. Acid-base titrations. Heterogeneous equilibria in aqueous solution. Solubility and solubility product. States of aggregation. Experimental laws for gases. Vapor pressure. Phase transitions and phase diagrams. Solutions. Raoult law and deviations from ideality. Cryoscopy, ebullioscopy and osmotic pressure. Colligative properties and deviations from ideality for electrolytes. Electrochemistry. Batteries. Anode and cathode. Electrodes. Nernst formula. FEM of a cell. Concentration cells. pH meter. Electrolysis. Electrolytes, processes at the electrodes. Faraday's laws. Chemical kinetics. Reaction rate and related factors. Reaction mechanisms. Theories of collisions and of activated complex. Catalysts. Laboratory: equipment and general techniques. Chemical reactions in aqueous solution. Identification tests of different types. Qualitative analysis. RECOMMENDED READING/BIBLIOGRAPHY There is not a unique reference textbook, but the most of the material used during lectures is largely reported on Aulaweb. The recommended reference books are the followings, partly available at DCCI library: R. Chang, K. Goldsby, Fondamenti di Chimica Generale- McGraw-Hill – 2014 R. C. Bauer, J.P. Birk, P.S. Marks. Introduzione alla chimica, un approccio concettuale, II ed., Piccin, Padova, 2011 Nivaldo J. Tro, Chimica, un approccio molecolare, EdiSES, Napoli, 2017 Nivaldo J. Tro, Introduzione alla chimica, Pearson, 2013 P. Giannoccaro – S. Doronzo - Elementi di Stechiometria - EdiSES 2009 TEACHERS AND EXAM BOARD DANIELE MACCIO' Exam Board DANIELE MACCIO' (President) NADIA PARODI GILDA ZANICCHI LESSONS LESSONS START October 1, 2018 Class schedule GENERAL AND INORGANIC CHEMISTRY+LABORATORY EXAMS EXAM DESCRIPTION The exam consists of a written test and an oral interview. Passing the written test is mandatory for access to the oral exam. The final vote takes account of both components. ASSESSMENT METHODS The written tests take place in the academic holiday, the dates published in the course of study site (www.biotecnologie.unige.it). The oral interview generally place a few days later, according to the availability of Committee and the needs of the students. The days of written test will be indicated in the site www.biotecnologie.unige.it, Through the written test the ability to apply the acquired theoretical concepts is evaluated, while in the oral test the acquisition of theoretical knowledge is examined. Access to the oral test is allowed only to students obtaining a minimum score of 18/30 in written exam. Partecipation to all the laboratory exercises is compulsory to be admitted to the oral exam Exam schedule Data appello Orario Luogo Degree type Note 18/01/2019 10:00 GENOVA Scritto 15/02/2019 10:00 GENOVA Scritto 21/06/2019 10:00 GENOVA Scritto 19/07/2019 10:00 GENOVA Scritto 13/09/2019 10:00 GENOVA Scritto FURTHER INFORMATION For other questions about the course, write to the teacher at maccio@chimica.unige.it