AIMS AND CONTENT

LEARNING OUTCOMES

The course aims to provide the student with an updated overview in the field of inorganic functional materials with particular attention to synthesis techniques, techniques for a controlled modification of materials and their most current applications.

AIMS AND LEARNING OUTCOMES

This course aims at understanding the big role of functional materials in modern technologies and the working methodology in material research through the study of different classes of materials.

At the end of the course, stdents are expected to understand:

- Functionalities of materials used as sensors ans actuators.

- Working principles of different classes of functional materials.

- Main techniques of synthesis of tehse materials.

- Chemical and physical parameters allowing to improve devices performances

PREREQUISITES

Fundamentals of chemistry and physics

TEACHING METHODS

Traditional lectures from the teacher and, when possible, seminars given by experts at international level. Students can use material uploaded in Aulaweb. Partecipation to the lecture is strongly recommended.

SYLLABUS/CONTENT

Course objectives. Definition of functional materials and its relations to smart materials. Trasducers, sensors and actuators. Use of sensors in high technological devices (e.g. smartphones). MEMS. Synthesis methods for amorphous and crystalline materials. Solid-state reaction. Mechanochemical synthesis. Ceramic synthesis. Sintering Process. Combustion synthesis. Intercalation reactions. Formation of solids from solutions and melts: sol-gel processes and precursors. Solvothermal synthesis. Intercalation reactions. Layered host lattice, different charged layers and stages. Grafting reactions. Pillaring reactions. Intercalation compounds: graphite layered, metallic dichalcogenides. Hydrotalcite like-compounds. Nanostructured materials. Single crystals growing in functional materials. p-n junction. Diode Examples of application of p-n junctions. Semiconductor materials list. Methods for single crystal production of semiconductors: Czochralski process, Float-zone growing, Bridgman technique. Wafer production of Si -p and –n doped. Thin-film deposition techniques. Classification of thin-film deposition technology. Physical vapor deposition and chemical vapor deposition. Examples of use in different fields. Evaporation step. Knudsen number. Step coverage. Deposition steps. Epitaxy. Fractional mismatch. Substrates for epitaxy. Heteroepitaxy of semiconductors. Epitaxy techniques (LPE, VPE, MBE, MOCVD). Energy beams: electron beams, cathodic and anodic arc, pulsed beams, ion-beams sputtering. Chemical vapor deposition (CVD) and comparison with PVD. Gas transport, reactors and typical overall reactions used in CVD. Precursors. Case exemplary study: Deposition of SiO2.

Examples of functional materials

LED (Light emitting diodes). From IR-LEDs to visible LEDS. Case exemplary study: more than 30 years in order to obtain efficient blue LED. Thermoelectric materials. Seebeck and Peltier effects. . Figure of merit zT. Thermoelectric modules. Phonon-glass electron crystal (PGEC). Applications.  Shape memory alloys (SMA). Martensitic transformation. Shape memory effect. Superelasticity. Applications. Piezoelectrics. Piezoelectricity and crystal symmetry. Lead zirconate titanate (PZT) and other perovskitic materials. Applications.  Rechargeable Lithium ion batterie and Supercapacitors. Energy storage: batteries vs supercapacitors. Roching Chair of Li-ion. Choice of electrodes.  Supercapacitors and materials of choice.

RECOMMENDED READING/BIBLIOGRAPHY

Inorganic materials, D.W.Bruce, D.O’Hare, J.Wiley&Sons, 1997

Synthesis of Inorganic Materials, U.Schubert, N.Hüsing, Wiley-VCH, 2012

Introduzione alla chimica dei materiali, G.Flor, C. Tealdi, Dispenseonline, Pavia, 2009

Basic Solid State Chemistry, A.R.West, Wiley-VCH, 1984

Solid State chemistry, Anthony R. West, J. Wiley e Sons 1990

TEACHERS AND EXAM BOARD

LESSONS

LESSONS START

From February 26, 2024

Class schedule

The timetable for this course is available here: Portale EasyAcademy

EXAMS

EXAM DESCRIPTION

Exams will consist of a written and an oral examinations. Oral examinations will last at least 40 minutes. 

ASSESSMENT METHODS

Both examinations (the oral examination lasting at least 30 minutes) allow to check accurately the achievement of the educational goals of the course. During the course assignements to be presented orally will be given to students.

FURTHER INFORMATION

http://www.chimica.unige.it/en/teaching/msc-degrees

Students who have valid certification of physical or learning disabilities on file with the University and who wish to discuss possible accommodations or other circumstances regarding lectures, coursework and exams, should speak both with the instructor and with Professor Sergio Di Domizio (sergio.didomizio@unige.it), the Department’s disability liaison.