OVERVIEW

The study of systems in which chemical and physical transformations occur cannot be isolated from thermodynamic and kinetic considerations, which mathematically explore the exchanges of energy, matter, and the rate at which these exchanges occur. The teaching aims to provide students with the fundamentals of classical thermodynamics, such as the concept of energy associated with chemical-physical transformations and the determination of thermodynamic variables and functions associated with reactions; as well as concepts related to reaction rates, both in the gas phase and in aqueous solution, reaction order, and the role of catalysts.

AIMS AND CONTENT

LEARNING OUTCOMES

The teaching aims to provide students with the fundamental concepts of thermodynamics applied to chemical systems, such as the heat and energy associated with phase transformations and chemical reactions. The concept of chemical equilibrium is considered as a function of environmental variables, typically pressure and temperature, so the student will be able to evaluate the most energetically favorable conditions for predicting how to advance (or move backward, whether necessary) a reaction as a function of the equilibrium and its evolution along time. Fundamental aspects of reaction kinetics for both gas-phase systems and aqueous solutions will also be presented, intended to support the ability to define the reaction order and determine the kinetic equation; the progress of chemical reactions in the presence of catalysts, both homogeneous and heterogeneous, will also be explored.

AIMS AND LEARNING OUTCOMES

The teaching aims to provide students with the fundamental concepts of thermodynamics applied to chemical systems, such as the heat and energy associated with phase transformations and chemical reactions. The concept of chemical equilibrium is considered as a function of environmental variables, typically pressure and temperature, so the student will be able to evaluate the most energetically favorable conditions for predicting how to advance (or move backward, whether necessary) a reaction as a function of the equilibrium and its evolution along time. Fundamental aspects of reaction kinetics for both gas-phase systems and aqueous solutions will also be presented, intended to support the ability to define the reaction order and determine the kinetic equation; the progress of chemical reactions in the presence of catalysts, both homogeneous and heterogeneous, will also be explored.

PREREQUISITES

No official prerequisites, but it is recommended to have overcome the exams of Elements of Chemistry and Elements of Materials Science.

TEACHING METHODS

Students who have valid certification of physical or learning disabilities on file with the University and who wish to discuss possible accommodations or other circumstances regarding lectures, coursework and exams, should speak both with the instructor and with Professor Federico Scarpa (federico.scarpa@unige.it  ), the Polytechnic School's disability liaison.

RECOMMENDED READING/BIBLIOGRAPHY

M. Compiani, C. La Rosa, P. Sassi – CHIMICA FISICA – UTET (2023)

P. W. Atkins e J. De Paula – CHIMICA FISICA – Zanichelli (varie edizioni)

A. Gambi - ESERCIZI DI CHIMICA FISICA - Zanichelli

TEACHERS AND EXAM BOARD

Exam Board

MAURIZIO FERRETTI (President)

STEFANO ALBERTI

MAILA CASTELLANO

MARINA ALLOISIO (President Substitute)

FEDERICO LOCARDI (President Substitute)

SILVIA VICINI (President Substitute)

LESSONS

LESSONS START

https://corsi.unige.it/corsi/11429/studenti-orario

Class schedule

The timetable for this course is available here: Portale EasyAcademy

EXAMS

EXAM DESCRIPTION

The examination consists of a written test; the time available for the test is 120 minutes. Number and distribution of official rounds during the academic year are set according to the guidelines established by the Study Manifesto and the Regulations of the Course of Study. The written test consists of 10 open-ended questions, for each of which a score of no more than 3 points is given.

Students who have valid certification of physical or learning disabilities on file with the University and who wish to discuss any accommodations or other circumstances related to classes, courses and examinations should speak with both the lecturer and Prof. Federico Scarpa (federico.scarpa@unige.it), dedicated contact person for the Polytechnic School.

ASSESSMENT METHODS

The purpose of the written test is to verify the actual achievement of the educational objectives of the teaching in detail, which correspond to the expected student learning outcomes listed in the dedicated section. The written test, as it is structured, is dedicated to verifying the achievement of an adequate level of basic knowledge of the program and understanding of the topics covered. It will also be possible for the student to independently verify his or her level of preparation through active participation in lectures and exercises. Further details of exam preparation methods will be provided during the teaching.